王凯,汉族,湖南汨罗人。博士,教授。
电子邮箱:kaiwang@glut.edu.cn
一、教育工作经历
2016.09至今:伟德betvlctor体育官网,伟德betvlctor体育官网任教。
2009.07-2016.07:桂林师范高等专科学校,化学与药学系任教。
2011.09-2015.06:南京大学,配位化学国家重点实验室,无机化学专业,获理学博士学位。
2006.09-2009.06:广西师范大学,化学与药学学院,有机化学专业,获理学硕士学位。
2002.09-2006.06:广西师范大学,化学与药学学院,化学专业,获理学学士学位。
二、教学工作
主要承担《无机化学》、《普通化学》、《大学化学》等本科生课程,《单晶结构解析》等研究生课程。主持广西高等教育本科教学改革工程项目1项,参编《普通化学》与《有机化学化学》教材2部。
教学奖励:
1)广西高校老员工化学实验技能竞赛“优秀教练员”;
2)第八届广西青年教师教学竞赛三等奖;
3)伟德betvlctor体育官网第十八届“十佳授课教师”;
4)指导本科生获广西老员工课外学术科技作品竞赛特等奖1项、二等奖1项;
5)指导本科生获广西高校老员工化学化工类论文及设计竞赛一等奖1项、二等奖3项;
6)指导本科生获广西高校老员工化学实验技能竞赛一等奖5项,二等奖2项,三等奖3项;
7)指导硕士研究生林超斌、郭柯柯获广西青年学术年会论文一等奖1项;
8)指导硕士研究生郭柯柯获2019年伟德betvlctor体育官网优秀研究生学位论文;
9)指导硕士研究生苏森达获2019年伟德betvlctor体育官网优秀研究生学位论文;
10)指导硕士研究生罗学晶获2022年伟德betvlctor体育官网优秀研究生学位论文;
11)指导硕士研究生朱孟孟获2023年伟德betvlctor体育官网优秀研究生学位论文。
三、科研工作
主要从事稀土分子基材料的设计合成及其在磁性、光磁响应性与光催化有机合成反应等方面的研究。现主持国家自然科学基金1项,主持完成广西自然科学基金2项、广西高校科研项目1项;已在Chinese Chem. Lett.、Chem. Commum.、Inorg. Chem.、Cryst. Growth Des.、Dalton Trans.、Adv Synth Catal.等重要学术刊物上发表SCI论文30余篇,参编学术专著1部;曾获2012年广西自然科学奖三等奖1项。
科研项目:
1)国家自然科学基金:稀土单分子磁体中单离子磁各向异性与磁交换作用协同的机制与调控研究,21961008,主持;
2)广西自然科学基金面上项目:双核稀土单分子磁体的合成、弛豫机理与磁构关系研究,2018GXNSFAA138123,主持;
3)广西自然科学基金青年基金:配体调控的Gd基配合物合成及其磁制冷性质研究,2014GXNSFBA118055,主持;
4)国家自然科学基金:稀土分子基多铁性材料合成及性能研究,21771043,参与;
5)广西自然科学基金重点项目:稀土高核簇合物的组装及其磁学性质研究,2015GXNSFDA139007,参与。
研究论文:
1)Peng S.; Ouyang, X. M.; Wang, Y. H.; Teng, Q. H.*; Li, Y.; Zhang, X. Q.; Hu, Z. B.; Wang, K.*; Liang, F. P.* In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases, Chinese Chem. Lett., 2023, 34, 108044.
2)Luo, X. J.; Liu, Y.; Pan, H. D.; Peng, S.; Hu, Z. B.*; Teng, Q. H.; Li, Y.; Liang, F. P.*, Wang, K.* Photoresponsive magnetic relaxation behavior of a highly stable π···π interaction-stacked framework based on a DyIII single-ion magnet. Cryst. Growth Des., 2023, 23, 4825–4835.
3)Chen, J. H.; Peng, S.; Pan, H. D.; Wu, C. E.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Liang, F. P.*, Wang, K.* Dysprosium clusters from 3-ethoxysalicylidene terminal-decorated acylhydrazone ligands: in situ ligand-transformation-assisted assembly and zero field single-molecule magnet behaviors. Cryst. Growth Des., 2023, 23, 4927–4938.
4)Teng, Q. H.*; Sun, G. X.; Huang, F. P.; Wang, K.*; Liang, F. P.* Visible-light induced Cerium-catalyzed N-demethylation of N-methyl amides under air conditions. Adv Synth Catal., 2023, 365, 307–311.
5)Liu, L.; Yang, P. P.; Qiu, Z. H.*; Wang, K.*; Liu, D. C.; Liang, Y. N.; Hu, H. C.; Zou, H. H.; Liang, F. P.; Chen, Z. L*. Russian Doll-Like 3d-4f Cluster Wheels with Slow Relaxation of Magnetization. Molecules, 2023, 28, 5906.
6)Wang, Y. H.; Qin, Y.; Tang, S.; Teng, Q. H.*; Zhu, M. M.; Peng, S.; Wang, K.*; Liang, F. P.* Asymmetric {Dy4} Metallogrid and Double-Layered {Dy8} cage clusters from carboxylic decorated o-vanillin schiff bases: syntheses, topological variation, and single molecule magnet behaviors. New J Chem., 2023, 47, 2052–2059.
7)Zhu, M. M.; Pan, H. D.; Teng, Q. H.*; Liang, F. P.*, Wang, K.* Slow magnetic relaxation behavior of a {Dy2} complex based on large π-conjugated bridging ligand. Polyhedron, 2023, 232, 1116271.
8)Pan, H. Dong.; Wu, C. E., Chen, J. H.; Li, Y.; Zhang, X. Q.; Teng, Q. H.*; Wang, K.*; Liang, F. P.* A pair of 2D MOFs based on [Tm2] secondary building units: syntheses, structural variation and magnetic properties. J Clust. Sci., 2023, 34, 1769–1776.
9)Kong, F. Y.; Han, H. Z.; Huang, S. X.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Zhu, L.*; Wang, K.*; Liang, F. P.* A pair of chiral dysprosium single-ion magnets with 2,6-bis[(4S/4R)4-phenyl-2-oxazolinyl]pyridine and hexafluoroacetylacetonate ligands. Russ. J. Coordin. Chem., 2022, 48, 667–674.
10)Teng, Q. H.; Sun, G. X.; Luo, S. Y.; Wang, K.*; Liang, F. P.* Design, syntheses and antitumor activities evaluation of 1,5-diaryl substituted pyrazole secnidazole ester derivatives. J Heterocyclic Chem., 2021, 58, 1656–1664.
11)Xu, F.; Luo, X. J.; Wu, C. E.; Liao, B. Y.; Wang, K.*; Liang, F. P.* A quasi-liner {MnIIDyIIIMnII} cluster featuring in situ Schiff base ligand transformation. J Clust. Sci., 2021, 32, 1411–1418.
12)Huang, S. X.; Xu, F.; Qi, S. J.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Luo, S. Y.*; Liang, F. P.* A double-layered {Cu9} nanocage with diacylhydrazine: synthesis, structure and magnetic properties. J Clust. Sci., 2021, 32, 765–772.
13)Lin, C. B.; Guo, K. K.; Guo, W. X.; Wang, Y. H.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* Rationally designing MOFs based on [Ln2] magnetic building blocks utilizing 2-hydroxyisophthalate and fine-tuning the magnetic properties of Dy analogues by terminal coordinated solvents. Inorg. Chem., 2020, 59, 16924−16935.
14)Su, S. D.; Li, J. X.; Xu, F.; Wang, C. X.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* DyIII single-molecule magnets from ligands incorporating both amine and acylhydrazine Schiff base groups: the centrosymmetric {Dy2} displaying dual magnetic relaxation behaviors. Dalton Trans., 2020, 49, 15739–15749.
15)Su, S. D.; Ou-Yang, X. M.; Guo, K. K.; Lin, Q. M.; Li, Y.; Wang, K.*; Luo, S. Y.*; Liang, F. P.* Synthesis, structure and magnetic properties of a Fe(III) [24-azaMC-8] azametallacrown nanocluster with diacylhydrazine ligand. J Clust. Sci., 2019, 30, 863–868.
16)Guo, K. K.; Su, S. D.; Shen, Y. L.; Wang, K.*; Li, Y.; Zhang, X. Q.; Li, B.*; Zou, H. H.; Liang, F. P.* A [Cu3] cluster-based chain featuring linkages of acylhydrazone N–N Single Bonds and Cl- ions: synthesis, structure and magnetic properties. J Clust. Sci., 2019, 30, 219–224.
17)Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, S. H.; Li, Y.; Zhang, X. Q.; Sun, W. Y.; Liang, F. P.* Diacylhydrazone assembled {Ln11} nanoclusters featuring a “double-boats conformation” topology: synthesis, structures and magnetism. Dalton Trans., 2018, 47, 2337–2343.
18)Wang, K.; Tang S.; Hu, Z. B.; Zou, H. H.; Wang, X. L.; Zhang, S. H.; Li, Y.; Chen, Z. L.; Liang, F. P.* A family of 3d metal clusters based on N–N single bonds bridged quasi-linear trinuclear cores: the Mn analogue displaying single-molecule magnet behavior. RSC Adv., 2018, 8, 6218–6224.
19)Wang, K.; Chen, Z. L.; Zou, H. H.; Li, Y.; Liang, F. P.* A series of 3d complexes from in-situ reactions of a flexible diacylhydrazine ligand: synthesis, structures and magnetic properties. Transit. Metal Chem., 2017, 42, 17–23.
20)Wang, K.; Chen, Z. L.; Zou, H. H.; Hu, K.; Li, H. Y.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A single-stranded {Gd18} nanowheel with symmetric polydentate diacylhydrazone ligand. Chem. Commun., 2016, 52, 8297−8300.
21)Wang, K.; Huang, X. K.; Zhu. L.; Chen, Z. L.; Liang, F. P.* A chain Cadmium(II) coordination polymer with diacylhydrazide: synthesis, crystal structure and luminescent property. Chin. J. Struct. Chem., 2016, 35, 1912-1919.
22)Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* Two types of Cu-Ln Heterometallic coordination polymers with 2-hydroxyl isophthalate: syntheses, structures and magnetic properties. Cryst. Growth Des., 2015, 15, 2883−2890.
23)Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* One-dimensional Co(II)/Ni(II) complexes of 2−hydroxyl isophthalate: structures and magnetic properties. J. Solid State Chem., 2015, 226, 36−41.
24)Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescent properties. Dalton Trans., 2014, 43, 12989−12995.
25)Wang, K.; Liu, X. X.; Yi, X. H.; Wang, H. S.; Zhang, Y.; Pan, Y. M.* Synthesis and metal ion binding activity of methyl 12-amino-13-nitro-7-oxo dehydrodeisopropylabietate derivatives. Med. Chem. Res., 2012, 21, 2494−2500.
26)Wang, K.; Zhang, Y.; Ekunwe, S. I. N.; Yi, X. H.; Liu, X. X.; Wang, H. S.; Pan, Y. M.* Antioxidant activities and inhibition effect of esculetin from Cortex Fraxini on the growth of human colon carcinoma (HT-29) cells. Med. Chem. Res., 2011, 20, 968–974.
27)Wang, K.; Pan, Y. M.;* Wang, H. S.; Zhang, Y.; Lei, Q.; Zhu, Z. R.; Li, H. Y.; Liang, M. Antioxidant activities of Liquidambar formosana Hance leaf extracts. Med. Chem. Res., 2010, 19, 166−176.
授权专利:
1)王凯,罗学晶,滕青湖,梁福沛;一种兼具高稳定性与光刺激响应性的镝基单离子磁体超分子框架及其合成方法;专利号CN202210262448.5。
2)王凯,王亦寒,秦雨,梁福沛;一种有序封装四硫富瓦烯客体的光刺激响应性铕基金属有机框架;专利号CN202211543450.6。
3)王凯,郭柯柯,黄生学,梁福沛;一种具有磁制冷效应的二维钆基化合物及其制备方法;专利号:CN201810861783.0。